3,298 research outputs found
Quantum initial condition sampling for linearized density matrix dynamics: Vibrational pure dephasing of iodine in krypton matrices
This paper reviews the linearized path integral approach for computing time
dependent properties of systems that can be approximated using a mixed
quantum-classical description. This approach is applied to studying vibrational
pure dephasing of ground state molecular iodine in a rare gas matrix. The
Feynman-Kleinert optimized harmonic approximation for the full system density
operator is used to sample initial conditions for the bath degrees of freedom.
This extremely efficient approach is compared with alternative initial
condition sampling techniques at low temperatures where classical initial
condition sampling yields dephasing rates that are nearly an order of magnitude
too slow compared with quantum initial condition sampling and experimental
results.Comment: 20 pages and 8 figure
Predicting and verifying transition strengths from weakly bound molecules
We investigated transition strengths from ultracold weakly bound 41K87Rb
molecules produced via the photoassociation of laser-cooled atoms. An accurate
potential energy curve of the excited state (3)1Sigma+ was constructed by
carrying out direct potential fit analysis of rotational spectra obtained via
depletion spectroscopy. Vibrational energies and rotational constants extracted
from the depletion spectra of v'=41-50 levels were combined with the results of
the previous spectroscopic study, and they were used for modifying an ab initio
potential. An accuracy of 0.14% in vibrational level spacing and 0.3% in
rotational constants was sufficient to predict the large observed variation in
transition strengths among the vibrational levels. Our results show that
transition strengths from weakly bound molecules are a good measure of the
accuracy of an excited state potential.Comment: 7 pages, 7 figure
Experimental evidence of thermal fluctuations on the X-ray absorption near-edge structure at the aluminum K-edge
After a review of temperature-dependent experimental x-ray absorption
near-edge structure (XANES) and related theoretical developments, we present
the Al K-edge XANES spectra of corundum and beryl for temperature ranging from
300K to 930K. These experimental results provide a first evidence of the role
of thermal fluctuation in XANES at the Al K-edge especially in the pre-edge
region. The study is carried out by polarized XANES measurements of single
crystals. For any orientation of the sample with respect to the x-ray beam, the
pre-edge peak grows and shifts to lower energy with temperature. In addition
temperature induces modifications in the position and intensities of the main
XANES features. First-principles DFT calculations are performed for both
compounds. They show that the pre-edge peak originates from forbidden 1s to 3s
transitions induced by vibrations. Three existing theoretical models are used
to take vibrations into account in the absorption cross section calculations:
i) an average of the XANES spectra over the thermal displacements of the
absorbing atom around its equilibrium position, ii) a method based on the crude
Born-Oppenheimer approximation where only the initial state is averaged over
thermal displacements, iii) a convolution of the spectra obtained for the atoms
at the equilibrium positions with an approximate phonon spectral function. The
theoretical spectra so obtained permit to qualitatively understand the origin
of the spectral modifications induced by temperature. However the correct
treatment of thermal fluctuation in XANES spectroscopy requires more
sophisticated theoretical tools
Ab initio Molecular Dynamics in Adaptive Coordinates
We present a new formulation of ab initio molecular dynamics which exploits
the efficiency of plane waves in adaptive curvilinear coordinates, and thus
provides an accurate treatment of first-row elements. The method is used to
perform a molecular dynamics simulation of the CO_2 molecule, and allows to
reproduce detailed features of its vibrational spectrum such as the splitting
of the Raman sigma+_g mode caused by Fermi resonance. This new approach opens
the way to highly accurate ab initio simulations of organic compounds.Comment: 11 pages, 3 PostScript figure
On the Prospects for Laser Cooling of TlF
We measure the upper state lifetime and two ratios of vibrational branching
fractions f_{v'v} on the B^{3}\Pi_{1}(v') - X^{1}\Sigma^{+}(v) transition of
TlF. We find the B state lifetime to be 99(9) ns. We also determine that the
off-diagonal vibrational decays are highly suppressed: f_{01}/f_{00} <
2x10^{-4} and f_{02}/f_{00} = 1.10(6)%, in excellent agreement with their
predicted values of f_{01}/f_{00} < 8x10^{-4} and f_{02}/f_{00} = 1.0(2)% based
on Franck-Condon factors calculated using Morse and RKR potentials. The
implications of these results for the possible laser cooling of TlF and
fundamental symmetries experiments are discussed.Comment: 5 pages, 2 figure
Molecular Dipolar Crystals as High Fidelity Quantum Memory for Hybrid Quantum Computing
We study collective excitations of rotational and spin states of an ensemble
of polar molecules, which are prepared in a dipolar crystalline phase, as a
candidate for a high fidelity quantum memory. While dipolar crystals are formed
in the high density limit of cold clouds of polar molecules under 1D and 2D
trapping conditions, the crystalline structure protects the molecular qubits
from detrimental effects of short range collisions. We calculate the lifetime
of the quantum memory by identifying the dominant decoherence mechanisms, and
estimate their effects on gate operations, when a molecular ensemble qubit is
transferred to a superconducting strip line cavity (circuit QED). In the case
rotational excitations coupled by dipole-dipole interactions we identify
phonons as the main limitation of the life time of qubits. We study specific
setups and conditions, where the coupling to the phonon modes is minimized.
Detailed results are presented for a 1D dipolar chain
High-resolution Fourier-transform XUV photoabsorption spectroscopy of 14N15N
The first comprehensive high-resolution photoabsorption spectrum of 14N15N
has been recorded using the Fourier-transform spectrometer attached to the
Desirs beamline at the Soleil synchrotron. Observations are made in the extreme
ultraviolet (XUV) and span 100,000-109,000 cm-1 (100-91.7 nm). The observed
absorption lines have been assigned to 25 bands and reduced to a set of
transition energies, f values, and linewidths. This analysis has verified the
predictions of a theoretical model of N2 that simulates its photoabsorption and
photodissociation cross section by solution of an isotopomer independent
formulation of the coupled-channel Schroedinger equation. The mass dependence
of predissociation linewidths and oscillator strengths is clearly evident and
many local perturbations of transition energies, strengths, and widths within
individual rotational series have been observed.Comment: 14 pages, 8 figures, one data archiv
Dynamics of Bulk vs. Nanoscale WS_2: Local Strain and Charging Effects
We measured the infrared vibrational properties of bulk and nanoparticle
WS in order to investigate the structure-property relations in these novel
materials. In addition to the symmetry-breaking effects of local strain,
nanoparticle curvature modifies the local charging environment of the bulk
material. Performing a charge analysis on the \emph{xy}-polarized E
vibrational mode, we find an approximate 1.5:1 intralayer charge difference
between the layered 2H material and inorganic fullerene-like (IF)
nanoparticles. This effective charge difference may impact the solid-state
lubrication properties of nanoscale metal dichalcogenides.Comment: 6 pages, 5 figure
Strong fragmentation of low-energy electromagnetic excitation strength in Sn
Results of nuclear resonance fluorescence experiments on Sn are
reported. More than 50 transitions with MeV were
detected indicating a strong fragmentation of the electromagnetic excitation
strength. For the first time microscopic calculations making use of a complete
configuration space for low-lying states are performed in heavy odd-mass
spherical nuclei. The theoretical predictions are in good agreement with the
data. It is concluded that although the E1 transitions are the strongest ones
also M1 and E2 decays contribute substantially to the observed spectra. In
contrast to the neighboring even Sn, in Sn the
component of the two-phonon quintuplet built on top of
the 1/2 ground state is proved to be strongly fragmented.Comment: 4 pages, 3 figure
A new technique for elucidating -decay schemes which involve daughter nuclei with very low energy excited states
A new technique of elucidating -decay schemes of isotopes with large
density of states at low excitation energies has been developed, in which a
Broad Energy Germanium (BEGe) detector is used in conjunction with coaxial
hyper-pure germanium detectors. The power of this technique has been
demonstrated on the example of 183Hg decay. Mass-separated samples of 183Hg
were produced by a deposition of the low-energy radioactive-ion beam delivered
by the ISOLDE facility at CERN. The excellent energy resolution of the BEGe
detector allowed rays energies to be determined with a precision of a
few tens of electronvolts, which was sufficient for the analysis of the
Rydberg-Ritz combinations in the level scheme. The timestamped structure of the
data was used for unambiguous separation of rays arising from the
decay of 183Hg from those due to the daughter decays
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